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The moisture resistance of Kraft paper was greatly improved when it was coated with silylated soybean oil that was cured via silanol condensation. This moisture barrier coating was prepared from LowSat® Soybean oil that was grafted with vinyltrimethoxysilane (VTMS) using a relatively simple process based on the “Ene reaction”. The viscosity of the resulting oil was unaffected by the silylation reaction...
Silylation of non-terminal double bonds of unsaturated fatty acids with reactive organosilicons was successfully accomplished using the ‘Ene’ reaction route. The ‘Ene’ reaction, which is a subset of the famous Diels Alder reaction, enables grafting of vinyl silanes onto unsaturated organic molecules irrespective of the position of the double bond. This procedure was used to graft vinyltrialkoxysilanes...
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