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The effects of ionic additives on the catalytic activity and product distribution of hydrocarbons and oxygenates were studied on the reaction of quasi-homogeneous ruthenium nanoparticle (Ru NP) catalyst for aqueous phase Fischer–Tropsch synthesis (AFTS). A variety of potassium and sodium salts, as well as KOH and NaOH were used as the ionic additives in the AFTS reactions either after the synthesis...
Aqueous phase Fischer–Tropsch synthesis catalyzed by Ru nanoparticles was studied in a continuous flow reactor for the first time. A 60ml autoclave was used for catalyst screening and a 1000ml reactor was used to test the scale-up stability of the catalysts. Ru nanoparticles reduced by hydrogen in the presence of poly(N-vinyl-2-pyrrolidone) (PVP) showed the highest activity compared with those of...
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