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We determined the excess partial molar enthalpy and the excess partial molar volume, HTFEE, VTFEE, of 2,2,2-trifluoroethanol (TFE) in TFE-H2O at 25.0°C. We then evaluate the TFE-TFE interactions in terms of enthalpy and volume, HTFE-TFEE and VTFE-TFEE, graphically without resorting to any model dependent fitting functions. Both model-free third derivatives indicate that TFE is a hydrophobic solute...