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To investigate the potential of a fully aromatic, amorphous thermotropic liquid crystalline polyester (CPHNA60) as the in situ reinforcement component for poly(ethylene terephthalate) (PET) fibers, blends containing up to 10wt% of CPHNA60 were prepared, characterized and spun into fibers. DSC measurements of the blends revealed a nucleating effect of CPHNA60 and rheology investigations showed a decreased...
Via melt polycondensation two series of liquid crystalline thermotropic polyesters were synthesized for in situ reinforcement components in PET blend fibers. The copolymerization of a monomer bearing a bulky side group (tert-butyl hydrochinone) or a crankshaft monomer (6-acetoxy-2-naphthoic acid) with the non-coplanar 2,2′-dimethyl biphenol and terephthalic acid yielded two fully aromatic thermotropic...
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