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Alloy induced multivalency in transition metal oxides increases device functionality. Effects include insulator to metal transitions in the d0 perovskites (i) GdScO3, by substitution of tetravalent Ti trivalent for Sc, and (ii) LaMnO3 by alloy substitution of trivalent La and divalent Sr for trivalent La. Substitution of Ti3+ for Sc3+ on the ScO2 planes leads to hopping induced multivalencey for both...
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