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Water exchange between bulk water and water‐ion complexes will be at equilibrium when the charge density of the complex surface equals the charge density of bulk water, producing a constant radius water‐ion complex. This complex will migrate in an electric field at a velocity proportional to the complex radius. CE velocity is the sum of the complex charge‐dependent velocity and the buffer electro‐osmotic...
The dehydration of ion-water complexes prior to ion channel transit has focused on channel protein-mediated dissociation of water. Ion dehydration by the membrane electric field has not previously been considered. Near membrane electric fields have previously been shown to cause the disassociation of non-covalently bound small molecule-small molecule, small molecule-protein, and protein–protein complexes...
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