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Relationship between the structure and the thermal stability of poly(vinyl chloride) synthesized by various polymerization catalysts was investigated. The Cp∗Ti(OPh)/MAO catalyst, n-butyllithium (n-BuLi), the Cu(0)/TREN/CHBr 3 /DMSO catalyst, benzoyl peroxide/N,N-dimethylaniline (BPO/DMA), 2,2’-azobis(2.4-dimethylvaleronitrile) (V-65) was used as the polymerization catalyst. The temperature...
Bulk polymerization of vinyl chloride (VC) with Cp ∗ Ti(OPh) 3 /MAO catalyst was investigated. The bulk polymerization of VC with Cp ∗ Ti(OPh) 3 /MAO catalyst proceeded to give poly(vinyl chloride) (PVC) with high molecular weight in good yields. The M n of the polymer increased in direct proportion to polymer yields and the line passed through the origin. The...
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