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Sodium salts of ethyl N,N-dimethyl- and N,N-dimethylamidophosphoric acids I and II were obtained and their hydrolysis to respective acids was investigated. The salts and acids were characterized by spectral methods (MS, FT/IR, 1H, 13C, 31P NMR).
A new group of insecticides, widely introduced to the agriculture practice since the 90-ies of XX century - neonicotinoides, is discussed. The history of its arise, and insecticidal properties, mode of action, and short characteristics of some of its representatives is presented.
Ethyl (1S,2RS)-2-(2-chloropropanoyloxy)propanoate ((1S,2RS)-(I)) was obtained from rac-2-chloropropionyl chloride and ethyl L-lactate. (1S,2S)- (I) was also synthesized from (S)-2-chloropropionyl chloride and ethyl L-lactate with 93% d.e. (I) was undertaken hydrolysis by different media: NaOH/THF-H2O, Na2CO3/THF-H2O, LiOHxH2O/THF-H2O, 25% NaOH/H2O, and weakly acidic ion-exchange resin Amberlite IRC748...
The latest developed classes of synthetic insecticides – phthalic acid diamides and antranilic diamides, acting as ryanodine receptor modulators, are discussed. The mode of their activity, the insecticidal properties and characteristics of their representatives is reviewed.
The main component of Mediterranean flour moth (Anagasta kühniella Zell) pheromone (9Z,12E)-9,12-tetradecadien-1-ol acetate (ZETA) was obtained in the course of stereoselective Witting reaction of l-acetoxynonane-9-al with ylide generated from (3E)-pentenetriphenylphosphonium bromide in the presence of sodium bis(trimethylsilyl)amide (NaHMDS). Among the three adhesives CUSA, Estonia, Poland), evaluated...
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