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The formation of the trigonal structure of isotactic polypropylene (i-PP) in a series of random terpolymers of propylene (C3) with n-pentene-1 (C5) and n-hexene-1 (C6) by cooling from the molten state was investigated with the aim of assessing to what extent the intrinsic molecular disorder and the length of the side branch of the comonomers reflect on structuring kinetics and features of the crystal...
Low‐density polyethylene/layered double hydroxide (LDPE/LDH) nanocomposites were prepared via melt extrusion using organo‐LDH particles and maleic anhydride functionalized polyethylene as compatibilizer. Processing parameters, preparation method, and feed composition were properly modulated until obtaining nanocomposites with intercalated/exfoliated morphologies, and an uniform distribution of nanolayers,...
The melting and crystallization behaviour of a series of isotactic propene/1-pentene random copolymers, with 1-pentene contents up to 50mol%, was investigated by DSC and temperature resolved WAXD/SAXS. The role of the 1-pentene comonomer in the development of the trigonal modification (δ-form) of i-PP was studied and the results were compared with those reported in the literature for PP copolymers...
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