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Isothermal crystallization of the biodegradable homopolymer polyester poly(p-dioxanone) (PDS), and the p-dioxanone copolymer with glycolide PDS-copolymer were studied in situ and in real-time under quiescent or nucleation-enhancing shear conditions. It was found that the spherulitic growth rates remain unchanged with shear, while the nucleation density increases dramatically. Nucleation-enhancing...
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