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The oxidation of BF -4 -doped poly[(1,4-dimethoxybenzene)-co-(3-methylthiophene)] (PDMB-PMeTh) at 1.2 ± 0.1 V (vs. 10 -1 M Ag + Ag) in dry CH 3 CN + 0.2 M NEt 4 CN leads to a new CN-substituted copolymer. Comparative to the PDMB homopolymer, this electrochemical reaction is more efficiently performed, owing to better film properties provided by PMeTh...
Solutions of solvated electrons in the presence of magnesium offer many advantages for the surface treatment of PTFE when compared to the classical solutions of solvated electrons in the presence of alkalis: the polymer remains white instead of black, its surface is not destroyed and presents a controlled hydrophilic character.
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