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Theoretical analysis has been developed for the reduction process of the non-electroactive bromate anion via a redox-mediating cycle composed of the reversible Br2-to-Br− transformation at the electrode and of the irreversible (owing to high acidity of the solution) comproportionation reaction between Br− and BrO3− which regenerates Br2. Owing to the autocatalytic character of this cycle (EC″ mechanism)...
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