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Reaction of VOCl 3 with racemic trans-1,2-dithiacyclohexanediyl-2,2′-bis(6-tert-butyl-4-methylphenol) affords the chiral-at-metal vanadium(V) complex [V{(C 6 H 2 O-6-tert-Bu-4-Me) 2 S 2 C 6 H 10 }OCl] (1). The molecular structure of 1 was established by single crystal X-ray diffraction, which shows a cis-α configuration of the ligand around the...
Polyethylene (PE)–boehmite nanocomposites were prepared by means of metallocene/MAO-catalyzed in-situ polymerization of ethylene in the presence of boehmites, which were rendered organophilic by modification with carboxylic acids such as stearic acid and undecylenic acid. Such organoboehmites are readily dispersed in the polymerization media such as toluene. Polymerization activity, filler dispersion...
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