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The use of an intermediate reactive material composed of cerium (IV) oxide (ceria) is explored for solar fuel production through a CO2-splitting thermochemical redox cycle. To this end, powder and porous ceria samples are tested with TGA (thermogravimetric analysis) to ascertain their maximum fuel production potential from the CeO2 → CeO2−δ cycle. A maximum value of the non-stoichiometric reduction...
A new and potentially therapeutic diazirine, 4-aziadamantan-1-amine, was synthesized. Structural characterization also included single crystal X-ray diffraction analysis. Photolysis of the title compound in the solid phase afforded an azine. In contrast, pyrolysis in the gas phase gave two intramolecular carbene insertion products in a 4:1 ratio. A rationale for the observed diastereoselectivity is...
For the first time, the inclusion complex of any diazirine with a cyclodextrin was studied by single crystal X-ray diffraction. This and 2D NMR spectroscopy were employed to elucidate the structure in both the solid state and solution. An opposite orientation of the guest inside the host molecule was revealed. Moreover, crystallization of the neat guest enabled the first X-ray diffraction of a dialkyl-substituted...
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