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Several knowledge-based strategies for the efficient and consistent production of high performance emulsion polymers are discussed. These strategies involve the understanding of the effect of the process variables on polymer microstructure, as well as the development of quantitative polymer microstructure/product properties relationships. Case studies included tailoring adhesive properties, efficient...
Several knowledge-based strategies for the efficient and consistent production of high performance emulsion polymers are discussed. These strategies involve the understanding of the effect of the process variables on polymer microstructure, as well as the development of quantitative polymer microstructure/product properties relationships. Case studies included tailoring adhesive properties, efficient...
The efficiency of post-polymerization and devolatilization for residual monomer and VOC removal was investigated. It was found that mass transfer from aqueous phase to gas phase was the rate-determining step for devolatilization. The effect of the thermodynamic equilibrium coefficients on the latex devolatilization efficiency was studied. A strategy in which post-polymerization and devolatilization...
The efficiency of post-polymerization and devolatilization for residual monomer and VOC removal was investigated. It was found that mass transfer from aqueous phase to gas phase was the rate-determining step for devolatilization. The effect of the thermodynamic equilibrium coefficients on the latex devolatilization efficiency was studied. A strategy in which post-polymerization and devolatilization...
The main aspects of post-polymerization and devolatilization for cleaning industrial latexes were analyzed. Monomer partitioning was studied and we found that most of the monomer was portioned into the polymer particles, independently of its water solubility. The knowledge of the mechanisms involved in monomer removal by post-polymerization allowed the development of a mathematical model, which was...
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