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An electrochemical study of a series of mono- and biscarbene complexes of tungsten pentacarbonyl with mono- and dimeric heteroarene substituents are reported and compared in CH3CN and DCM. Results revealed that the order of oxidation (reduction) depends largely on the aryl substituent attached to the carbene carbon (2-thienyl, 2-furyl or 2-(N-methylpyrrolyl)). The order of oxidation (reduction) for...
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