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The species present in the vapours of CsBr and CsI have been isolated in krypton and xenon matrices and were investigated by FT-IR spectroscopy in the range of 180–30cm −1 . The recorded spectra revealed the presence of substantial amounts of dimer beside the alkali halide monomers. The assignment of the bands and characterization of the fundamentals was carried out on the basis of DFT quantum...
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