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Nearly monodispersed 1.6nm Ir, 2.3nm Pd nanoparticles, 2.7nm Pd(core)–Ir(shell) and 2.2nm Pd–Ir alloys with mixed surface atoms were synthesised in the presence of polyvinylpyrrolidone (PVP) and studied in the atmospheric ring opening of indan. The nanoparticles and supported catalysts were characterised by UV–vis spectroscopy, TGA, TEM, EDX, TPR, XPS, ISS and XANES. The nanoparticle size and structure...
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