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Vanadium multiredox‐based NASICON‐NazV2−yMy(PO4)3 (3 ≤ z ≤ 4; M = Al3+, Cr3+, and Mn2+) cathodes are particularly attractive for Na‐ion battery applications due to their high Na insertion voltage (>3.5 V vs Na+/Na0), reversible storage capacity (≈150 mA h g−1), and rate performance. However, their practical application is hindered by rapid capacity fade due to bulk structural rearrangements at...
Sodium superionic conductor (NASICON)‐Na4VMn(PO4)3 (NVMP) cathode is attractive for sodium‐ion battery application due to its reduced cost and toxicity, and high energy density (≈425 Wh kg−1). However, it exhibits significant polarization, limited rate and cycling performances due to its lower electronic conductivity and formation of Jahn–Teller active Mn3+ during cycling. In this report, a chemical...
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