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In comparison with other chemistries, little has been reported on sulfur‐containing plasma polymers; reasons include low volatility or high toxicity of monomers. Here, we report on plasma polymerization of dimethyl sulfoxide, by itself and its co‐polymerization with 1,7‐octadiene to generate S‐containing plasma polymers. Results show dominance of SS, SH, and SC with small percentages of SO and...
Phosphate groups are part of biological molecules involved in bio‐interfacial phenomena but monomers containing these groups are not volatile enough to be plasma polymerized (pp). Hence monomers with lower oxidation states of P are needed which then does not enable prediction of the oxidation state(s) of P in the pps, nor of possible aging effects. XPS and FTIR analyses of pps from triisopropyl phosphite...
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