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Direct electron transfer of cytochrome P450 from the thermoacidophilic crenarchaeon, Sulfolobus tokodaii strain 7, (P450st) entrapped onto the surface of a plastic formed carbon electrode in poly(ethylene oxide) (PEO) containing 0.5M KCl was achieved. The formal potential for wild-type P450st is −103mV (vs. Ag wire). Thermophilic P450st was modified with PEO having an average molecular weight of 2000...
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