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Different loadings of Pd ions in the B-site position of LaMnO 3 perovskites were investigated under methanol partial oxidation (MPO). Compared to pure LaMnO 3 , Pd-doped perovskites possessed greater reactivity. However, the correlation between Pd loadings with the catalytic activity of MPO was weak. The two Pd species, surface PdO and intracrystalline Pd ions, were identified. Surface...
Palladium integrated lanthanum-transition metal perovskites (LaMnO 3 , LaFeO 3 , and LaCoO 3 ) were employed in methanol partial oxidation to formaldehyde. The crystallinity of these perovskites remained unchanged by incorporating up to 5mol% Pd cations into their respective frameworks. Such a cation replacement could yield a positive effect on particle size and catalyst reducibility...
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