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Fourier transform infrared reflection absorption spectroscopy (FT-IRAS) has been used to probe the non-dissociative adsorption of N 2 on an atomically clean Pt(111) single crystal. In contradiction to a previous IRAS study of nitrogen adsorption on a Pt(111) foil at 120 K, no nitrogen infrared (IR) band was observed on a fully annealed Pt(111) surface at 90 K. Following Ar + ion bombardment,...
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