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Degradation of phenol by an electrochemical heterogeneous catalytic process was applied in packed bed electrolytic reactor with graphite electrode. The catalyst was characterized by SEM and the effects of pH, the applied potential and Na2SO4 on the efficiency of the electrochemical oxidation phenol process were also studied. It was found that the optimal condition was an applied potential of 25V,...
The kinetics of the oxidation of endocrine disruptor nonylphenol (NP) by potassium ferrate(VI) (K2FeO4) in water as a function of pH 8.0–10.9 at 25°C is presented. The observed second-order rate constants, kobs, decrease with an increase in pH 269–32 M−1 s−1. The speciation of Fe(VI) (HFeO 4− and FeO 42− ) and NP (NP–OH and NP–O−) species was used to explain the pH dependence of the kobs values....
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