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Nickel(0) complexes coordinatively unsaturated with 2,2"-bipyridine (bpy) are more reactive in the oxidative addition to organic halides than the saturated analogs. σ-Organonickel complexes formed as intermediates of catalytic cycles were prepared in high yields using nickel complexes coordinatively unsaturated with bpy and aromatic halides containing a methyl group in the ortho-position of the...
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