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A comprehensive thermodynamic framework for mixed-solvent electrolyte systems has been applied to the simultaneous computation of phase behavior and acid–base equilibria. The computational approach combines an excess Gibbs energy model with a formulation for standard-state properties of individual species and an algorithm for speciation calculations. Using this framework, a consistent methodology...
This study attempts to identify the soil properties controlling the fractionation of copper into various soil pools and determine the influence of pH and metal loading on soil-solution free copper activity (pCu2+). The pCu2+ was determined in 0.01 M CaCl2 soil extracts using a copper ion selective electrode. We analyzed a wide variety of soils: urban, agricultural and forest soils from the Province...
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