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Experimental studies of X-ray photoelectron and Co L_α X-ray emission spectra of the ZnS:Co semiconductor were carried out. It was established that Co ions are in a Co^{2+} configuration and that the Co 3d impurity states are localized above the top of the valence band by 1.0±0.2 eV.
Band structure investigations of the random MoNi_{4} and MoNi_{3} alloys, performed by emission and photoelectron spectroscopy, is reported. The X-ray emission and X-ray photoelectron spectra allowed to study the occupied valence band states below Fermi level. These techniques gave the full description of changes in the density of valence electron states distribution due to substitution of Mo atoms...
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