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The coordination geometries of metal sites in cupredoxins, mutants and metal derivatives of cupredoxins, multi-copper oxidases and a vanadium-containing chloroperoxidase as derived from X-ray crystallography are described. Correlations with their spectroscopic, electrochemical, electron transfer and catalytic properties are discussed. X-ray crystallography, EPR and Resonance Raman spectroscopy of...
Two catalytically distinct molybdenum-free dissimilatory nitrate reductases, a soluble periplasmic and a membrane-bound one, were isolated from the vanadate-reducing facultatively anaerobic bacterium Pseudomonas isachenkovii and purified to electrophoretic homogeneity. The enzymes did not contain molybdenum, the periplasmic enzyme contained vanadium, whereas the membrane-bound enzyme was vanadium-free...
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