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Compared with all‐small‐molecule (ASM) and other types of organic solar cells (OSCs), the small molecule donor:polymer acceptor (SMD:PA) OSCs develop much slower due to the lack of material matching rules. Herein, by changing the end‐cap substituent of the small molecule donor from ethyl (MPhS‐C2) to benzyl (MPhS‐Ph), the different selection rules of donor properties and thermal annealing (TA) treatment...
The commercialization of organic solar cells (OSCs) requires the use of roll‐to‐roll coating technology. However, it is generally believed that all‐small‐molecule (ASM) systems cannot form high‐quality films in most film‐fabrication technologies except for spin coating, mainly due to their strong crystallinity and low solution viscosity. Herein, it is found that the small molecule donor and acceptor...
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