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In g-C3N4/Bi2O3/BiPO4, the p–n junction between p-type Bi2O3 and n-type BiPO4 was encapsulated by g-C3N4 and a direct Z-scheme was built between g-C3N4 and Bi2O3. The optical, morphological and photoelectrochemical (PEC) properties of BiPO4, g-C3N4/BiPO4, Bi2O3/BiPO4 and g-C3N4/Bi2O3/BiPO4 hierarchical Z-scheme system were studied. More than 90% photodegradation of methyl orange (MO) with the exposure...