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Adsorption equilibria of three volatile organic compounds (VOCs) (acetone, toluene, and n-hexane) on mesoporous silica (MCM-41) were investigated over a wide range of supercritical and pressurized carbon dioxide conditions. Measurements of the adsorption equilibria were performed with a fixed bed method at temperatures from 313 to 353K and pressures from 4.2 to 15.0MPa. The measured adsorption equilibria...
A new prediction methodology by using the non-ideal adsorbed solution theory (NIAST) coupled with the Dubinin–Astakhov (DA) equation is proposed for volatile organic compounds (VOCs) (acetone, n-hexane, toluene, methanol and n-decane) adsorption equilibria under supercritical carbon dioxide conditions at temperatures from 313 to 353K and at pressures from 4.2 to 15.0MPa. Pure components adsorption...
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