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N,O-donating spacers are members of a class of ambidentate donors used in supramolecular self-assemblies. The skeletal adaptability and coordination flexibility of these ligands enable them to support a myriad of discrete molecular systems and extended network materials. This review focuses on pyridinecarboxylates as a representative of N,O-hetero-donating spacers and describes their recent developments...
Hydrothermal synthesis has afforded a family of four coordination polymers containing divalent nickel or cobalt and pendant-arm pyridylcarboxylate ligands. Utilizing 3-pyridylacetic acid and appropriate metal precursors produced [M(3-pyrac) 2 (H 2 O) 2 ] phases (M=Co (1); M=Ni (2)), while 3-pyridylpropionic acid generated [M(3-pyrprop) 2 (H 2 O) 2 ]...
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