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Pyrazolylethylphosphinite compounds, L1 (2-(3,5-dimethyl-1H-pyrazol-1-yl)ethyldiphenlyphosphinite) and L2 (2-(3,5-di-tert-butyl-1H-pyrazol-yl)ethyldiphenylphosphinite) were reacted with the palladium(II) precursors [PdCl(CH3)(COD)] and [PdCl2(NCCH3)2] resulted in the formation of five novel complexes, produced from disproportionation reaction and have very interesting coordination chemistry. The results...
Compounds (2‐(3,5‐dimethyl‐1H‐pyrazol‐1‐yl)ethyldiphenylphosphinite (L1), 2‐(3,5‐di‐tert‐butyl‐1H‐pyrazol‐1‐yl)ethyldiphenylphosphinite (L2), and 2‐(3,5‐diphenyl‐1H‐pyrazol‐1‐yl)ethyldiphenylphosphinite (L3) were prepared using the synthetic routes reported in literature. These compounds were reacted with [NiCl2(DME)2] or [NiBr2(DME)2] under appropriate reaction conditions to afford six new nickel(II)...
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