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The hydrosoluble complexes [Rh(CO)(Pz)(L)]2, and [RuH(CO)(CH3CN)(L)3][BF4] [L = TPPMS (triphenylphosphinemonosulfonated) and TPPTS (triphenylphosphine-trisulfonated)] were evaluated in the selective hydrogenation of α,β-unsaturated aldhydes in biphasic media The Rh complexes produced the saturated aldehydes while the Ru complexes generated the alcohols with high chemoselectivity. The catalytic phase...