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Complex formation equilibria between Ag(I) and thiourea or N-alkyl-substituted thioureas have been investigated in n-propanol by potentiometry at 10°C intervals from 5 to 50°C. Stepwise formation of tris-coordinated AgL n (n=1–3) complexes has been found for the majority of the ligands. ΔH and ΔS values for the complex formation reactions have been evaluated from the dependence of lnβ ...