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The Cu–Sn and Cu–Nb–Sn systems were optimized by the means of the CALPHAD (CALculation of PHAse Diagram) technique. The solution phases (liquid, fcc, bcc and bct), gamma and Cu 10 Sn 3 were described by the substitutional-solution model. The compounds Cu 3 Sn and Cu 41 Sn 11 in the Cu–Sn system were treated as (Cu,Sn) m (Cu,Sn) n . The compounds...