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New glasses following the P2O5‐CaO‐B2O3‐K2O‐MoO3 composition were prepared using the classical melt quenching method in order to investigate and correlate their structural peculiarities with the composition and, moreover, with the bioactivity and biocompatibility behavior. The structure and surface morphology of samples were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy...