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The behavior of the two-phase system consisting of a 30% solution of tri-n-butyl phosphate (TBP) in a paraffin diluent (C13) and a 12 M aqueous HNO3 solution was studied in the temperature interval from 70 to 110°С. The parameters of thermolysis of TBP solutions in C13 in the reaction with HNO3 in open vessels were determined with the aim of evaluating the explosion hazard of the system in the course...
The dynamics of gas evolution in the course of thermal oxidation of 30% solutions of tri-n-butyl phosphate (TBP) in C13 diluent, equilibrated with 12.9 M HNO3, was studied in open vessels in the temperature interval from 70 to 150°С. The total volumes of the released gases were measured, and the effect of the preliminary γ-irradiation of the TBP–С13–HNO3 system on the thermolysis of nitric acid and...
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