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Thermal decomposition of samarium nitrate hexahydrate Sm(NO3)3·6H2O has been investigated by thermogravimetry, differential scanning calorimetry, infrared spectroscopy, and X-ray diffractometry. This is a complex process that involves slow dehydration and fast concomitant internal hydrolysis. It is markedly different from the processes described for other members of the lanthanide series. At the first...
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