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The ternary inclusion complexes of two spin-labeled pyrrolidine-and piperidine-containing indole derivatives (1 and 2, respectively) and two hydrocarbons, benzene and cyclohexane, with γ-and β-cyclodextrins (CD) (altogether eight complexes) were prepared and studied by ESR in the solid phase over a broad temperature range. For most ternary complexes, the hydrophobicity of the NO group environment...
The interaction of ternary complexes γ-or β-cyclodextrin (CD)-spin-labeled indole (pyrrolidine (1) or piperidine (2) derivative)-hydrocarbon (benzene or cyclohexane) with the liquid phase of these hydrocarbons gives rise to a new type of complexes (s) the ESR spectra of which are indicative of a much lower rotational mobility and its weaker temperature dependence for the spin-labeled guests compared...
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