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Photogeneration of free charge carriers in poly{1-[4-(trimethylsilyl)phenyl]-2-phenylacetylene} has been studied theoretically. In our work we have utilized our data obtained previously using photoinduced discharge experiment, which showed a steep slope of the dependence of the free charge carriers photogeneration yield on the applied electric field at the low electric field limit, but no saturation...
A new theoretical insight into the process of free charge carrier photogeneration in polymers is introduced, based on the fact that increasing intensity of electric field may change the charge dynamics during the dissociation process of geminate pairs of photogenerated charge carriers. These changes are reflected in the model by the variation of internal parameters such as permittivity and effective...
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