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The acetate-based ionic liquid (AcIL) [EMIM][Ac] does not fully dissociated into isolated ions in extremely diluted water solution (0.5mol% of IL). Still, ion pairs exist via the through-space weak van der Waals force between H6 of the cation and Hb of the anion. In this ion pairs, except for H6 and Hb, all other hydrogen atoms (i.e., H2, H4, H5, H7, H8) are totally hydrated by water; the acetate...
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