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Four new isostructural lanthanide coordination polymers [Ln(Hcit)(H2O)2·2H2O]n (H4cit=citric acid) (Ln=Sm (1), Gd (2), Er (3), Nd (4)) have been synthesized under hydrothermal method by using citric acid, melamine as well as Sm(NO3)3·6H2O (1), Gd(NO3)3·6H2O (2), Er(NO3)3·6H2O (3), Nd(NO3)3·6H2O (4), and structurally characterized by FT-IR, thermogravimetric analyses (TGA), powder X-ray diffraction...
Magnetic moments: The orientation of the title single‐molecule magnet was investigated by magnetic single crystal and luminescence characterization, supported by ab initio calculations, and was found to be governed by the position of the hydrogen atoms of the apical water molecules. This finding suggests that simple magneto‐structural correlations can give misleading clues for research in molecular...
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