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Two new isostructural 3D lanthanide–organic frameworks [H2N(Me)2] [Ln3(OH)(bpt)3(H2O)3] (DMF)2⋅(H2O)4 (1‐Ln; Ln=Sm and Eu) with a 1D channel (25 Å) have been successfully assembled from the rare trinuclear [Ln3(OH)(COO)9] clusters and biphenyl‐3,4′,5‐tricarboxylic acid (H3bpt) and exhibit high stability towards water in the pH range 3–10. MOF 1‐Eu is a promising luminescent probe for sensing Fe3+...
Herein, a novel anionic framework with primitive centered cubic (pcu) topology, [(CH3)2NH2]4[(Zn4dttz6)Zn3]⋅15 DMF⋅4.5 H2O, (IFMC‐2; H3dttz=4,5‐di(1H‐tetrazol‐5‐yl)‐2H‐1,2,3‐triazole) was solvothermally isolated. A new example of a tetranuclear zinc cluster {Zn4dttz6} served as a secondary building unit in IFMC‐2. Furthermore, the metal cluster was connected by ZnII ions to give rise to a 3D open...
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