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Series of nickel and palladium complexes bearing amine−imine ligands in various ortho‐aryl and backbone positions were prepared and investigated in ethene polymerization. Ethene polymerization initiated by symmetrically ortho‐substituted nickel and palladium amine−imine catalysts is controlled. Mono‐substitution in the ortho‐aryl positions of nickel complexes is not as efficient in protecting centers...
A recently developed general kinetic approach, based on population balances in terms of generating functions, is applied to the modeling of the molecular architecture of branched copolymers produced through controlled radical polymerization (CRP) techniques, namely nitroxide‐mediated radical polymerization (NMRP) and atom‐transfer radical polymerization (ATRP). Thanks to this method, it is possible...
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