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Two phases are depicted in the cover image: the liquid phase and the gas phase, with ball‐and‐stick models of formic acid, CO2, and H2 in the corresponding phase. In the centre of the picture, there is a model of the famous Chinese blue‐and‐white porcelain, the color of which comes from cobalt pigment. On top of the porcelain is an X‐ray structure of the co‐complex developed for the dehydrogenation...
Among the known liquid organic hydrogen carriers, formic acid attracts increasing interest in the context of safe and reversible storage of hydrogen. Here, the first molecularly defined cobalt pincer complex is disclosed for the dehydrogenation of formic acid in aqueous medium under mild conditions. Crucial for catalytic activity is the use of the specific complex 3. Compared to related ruthenium...
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