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The traditional mesoporous silica (SBA-15) was synthesized by hydrothermal route. The swelling agents 1,3,5-trymethylbenzene (TMB) and heptane were used to expand the pore size and fluoride (NH4F) was used to modify the length of the pores, leading to porous silicas with different textural properties. The adsorbents, identified as SBA-15 (S), SBA-15 (S1) (TMB), SBA-15 (S2) (TMB and NH4F) and SBA-15...
The Langmuir-type adsorption of myoglobin occurred with monolayer coverage of the inner surface mesopore channels of SBA-15. Myoglobin occupation of the pores was calculated as ca. 50% based on N 2 adsorption/desorption isotherms. Pore-filling models revealed that myoglobin molecules are well packed in the pores. The maximum adsorption was observed near the isoelectric point of myoglobin,...
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