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Among nature's ecosystems, the marine environment has been an extremely rich source of structurally complex and biologically active molecules. This review aims to cover the recent developments in the synthesis of marine natural products, also reflecting the trend of their increased use to address biological questions. The examples chosen should be viewed as representative of the different structural...
In the late 1990s, the Caribbean octocoral Pseudopterogorgia elisabethae became the target of extensive chemical investigations leading to the isolation and characterization of a remarkable number of diterpenoid secondary metabolites. Most of these newly discovered compounds are based on so far unprecedented carbon skeletons and often feature unusual structural characteristics. Besides their exciting...
Medium-ring ethers, specifically those produced by the marine genus Laurencia, have attracted the attention of many synthetic chemists since 1965, when the isolation of laurencin, the first medium-ring ether from Laurencia, was reported by Irie. These medium oxacycles typically possess one or more halogen groups adjacent to an ethereal oxygen atom and an enyne or a bromoallene side chain. Therefore,...
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