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Lysocin E, a macrocyclic peptide, exhibits potent antibacterial activity against methicillin‐resistant Staphylococcus aureus (MRSA) through a novel mechanism. The first total synthesis of lysocin E was achieved by applying a full solid‐phase strategy. The developed approach also provides rapid access to the enantiomeric, epimeric, and N‐demethylated analogues of lysocin E. Significantly, the antibacterial...
Der marine Naturstoff Psymberin hat seit seiner Isolation großes Interesse hervorgerufen. Obwohl die hohe Zytotoxizität des Schwammextrakts früh bekannt war, brauchte es mehr als ein Jahrzehnt und weitere 600 Extraktfraktionen, bis seine chemische Struktur aufgeklärt werden konnte. In den letzten acht Jahren folgten diverse synthetische und biologische Untersuchungen sowie Studien der Struktur‐Aktivitäts‐Beziehungen,...
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