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Transition‐metal‐coordinated radicals can be hard to classify because the unpaired electron may be localized on the metal, the ligand, or delocalized on both. In metal complexes from the fourth period, with classical N‐ or O‐donor sites, the unpaired spin density is frequently on the metal. The paramagnetic cationic cobalt complex [Co(trop2N)(bpy)]+ may be described as a CoII amido complex or a Co...
A family of cobalt complexes bearing the trop2NH [bis(5‐H‐dibenzo[a,d]cyclohepten‐5‐yl)‐amine] and 2,2’‐bpy (2,2’‐bipyridine) chelate ligands were prepared and fully characterized. The compounds [Co(trop2N)(bpy)], [Co(trop2NH)(bpy)]+, and [Co(trop2N)(bpy)]+ are cobalt complexes interrelated by one‐electron redox processes and/or proton transfer. Two limiting resonance structures can be used to describe...
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